2.3.4_Full LITHIUM METAL BATTERIES CONTAINED IN EQUIPMENT FOR DISPOSAL OR RECYCLING Fully regulated batteries UN 3091 Applies to: Lithium metal batteries contained in equipment with a lithium content in excess of 25 g/battery UN No., Proper Shipping Name UN 3091, LITHIUM METAL BATTERIES CONTAINED IN EQUIPMENT Class 9 Packing Group Not assigned Hazard Label Labels must be in the form of a square set at an angle of 45° (diamond-shaped) with minimum dimensions of 100 mm by 100 mm; except for air transport mode, labels dimensions may be reduced not less then 30mm by 30mm on small packages. • They must have a line 5 mm inside the edge and running parallel with it. Prerequisite • For road transport, batteries do not need to meet the General Requirements of §173.185(a) in particular the test requirements Specific Requirements • Each battery incorporates a safety venting device or is designed to preclude a violent rupture under normal conditions of carriage; • Each battery is equipped with an effective means of preventing external short circuits Transport mode Road Marine Air Passenger Aircraft Cargo Packing instructions 173.185(d) P909 Forbidden Forbidden • Batteries and devices must be protected against short circuit, including protection against contact with conductive materials within the same packaging which could cause a short circuit. • Devices must be packed so that are protected against damage caused by the movement or placement of the cells within the packaging Packagings UN Packaging not required, strong outer packaging is authorized UN Packaging not required, strong outer packaging is authorized Cells ≥ 12 kg (gross) with a strong, impact resistant outer casing Not required UN approved packagings for batteries, or assemblies of such batteries, when packed in strong outer packagings or protective enclosures (e.g., fully enclosed or wooden slatted crates) Allowed transport on Pallets or other handling devices. Batteries must be secured to prevent inadvertent movement, and the terminals must not support the weight of other superimposed elements Large Packaging 173.185(b)(6) LP903 Rigid Large packagings, conforming to the packing group II performance level, are authorized for a single battery.: • steel (50A); • aluminium (50B); metal other than steel or aluminium (50N); • rigid plastics (50H); • natural wood (50C); • plywood (50D); • reconstituted wood (50F); • rigid fibreboard (50G). Weight limit No limit No limit Marking and Labelling of Packages UN 3091 LITHIUM METAL BATTERIES CONTAINED IN EQUIPMENT UN 3091 LITHIUM METAL BATTERIES CONTAINED IN EQUIPMENT Overpack: OVERPACK + same labels as above OVERPACK + same labels as above Documents Transport document Transport document Corrosive substances Risk of burns by May react vigoro and with other su Spilled substance Risk to the aqua system. 8 Miscellaneous dangerous substances and articles Risk of burns. Risk of fire. Risk of explosion Risk to the aqua system. 9 9A NOTE 1: For dangerous goods with mult NOTE 2: Additional guidance shown in c goods to be carried and their means of transpo 8 9 - 269 - Risk of vigorous reaction, ignition and explosion in contact with combustible or flammable substances. Avoid mixing with flammable or combustib substances (e.g. sawdust). 5.1 Organic peroxides Risk of exothermic decomposition at elevated temperatures, contact with other substances (such as acids, heavy-metal compounds or amines), friction or shock. This may result in the evolution of harmful and flammable gases or vapours or self-ignition. Avoid mixing with flammable or combustib substances (e.g. sawdust). 5.2 Toxic substances Risk of intoxication by inhalation, skin contact or ingestion. Risk to the aquatic environment or the sewerage system. Use emergency escape ma . 6.1 Infectious substances Risk of infection. May cause serious disease in humans or animals. Risk to the aquatic environment or the sewerage system. 6.2 Radioactive material Risk of intake and external radiation. Limit time of exposure. 7A 7B 7C 7D Fissile material Risk of nuclear chain reaction. 7E Corrosive substances Risk of burns by corrosion. May react vigorously with each other, with water and with other substances. Spilled substance may evolve corrosive vapours. Risk to the aquatic environment or the sewerage system. 8 Miscellaneous dangerous substances and articles Risk of burns. Risk of fire. Risk of explosion. Risk to the aquatic environment or the sewerage system. 9 9A NOTE 1: For dangerous goods with multiple risks and for mixed loads, each applicable entry shall be obser NOTE 2: Additional guidance shown in column (3) f the table may be adapted to reflect the classes of dan goods to be carried and their means of transport. - 269 - 5.1 5.2 5.2 6 6 RADIOACTIVE 7 8 9 - 269 - in contact with combustible or flammable substances. substa 5.1 Organic peroxides Risk of exothermic decomposition at elevated temperatures, contact with other substances (such as acids, heavy-metal compounds or amines), friction or shock. This may result in the evolution of harmful and flammable gases or vapours or self-ignition. Avoid substa 5.2 Toxic substances Risk of intoxication by inhalation, skin contact or ingestion. Risk to the aquatic environment or the sewerage system. Use e 6.1 Infectious substa ces Risk of infection. May cause serious disease in humans or animals. Risk to the aquatic environment or the sewerage system. 6.2 Radioactive material Risk of intake and external radiation. Limit 7A 7B 7C 7D Fissile material Risk of nuclear chain reaction. 7E Corrosive substances Risk of burns by corrosion. May react vigorously with each other, with water and with other substances. Spilled substance may evolve corrosive vapours. Risk to the aquatic environment or the sewerage system. 8 Miscellaneous dangerous substances and articles Risk of burns. Risk of fire. Risk of explosion. Risk to the aquatic environment or the sewerage system. 9 9A NOTE 1: For dangerous goods with multiple risks and for mixed loads, ea NOTE 2: Additional guidance shown in column (3) of the table may be ad goods to be carried and their means of transport. - 269 - 5.1 5.2 5.2 6 6 RADIOACTIVE 7 8 9 168 Copyrigh © w w.batteriestransport.org
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